Electrospun Sericin/PNIPAM-Based Nano-Modified Cotton Fabric with Multi-Function Responsiveness

L. Jia, Wang Boxiang, Cheng Dehong, Liu Zhimei, Lizhang Lv, Jingfeng Guo, Lu Yanhua
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引用次数: 7

Abstract

There is a significant interest in developing environmentally responsive or stimuli-responsive smart materials. The purpose of this study was to investigate multi-function responsive cotton fabrics with surface modification on the nanoscale. Three technologies including electrospinning technology, interpenetrating polymer network technology, and cross-linking technology were applied to prepare the multi-function sericin/poly(N-isopropylacrylamide)/Poly(ethylene oxide) nanofibers, which were then grafted onto the surfaces of cotton textiles to endow the cotton textiles with outstanding stimuli-responsive functionalities. The multi-function responsive properties were evaluated via SEM, DSC, the pH-responsive swelling behavior test and contact angle measurements. The results demonstrate that with this method, multi-function responsive, including thermo- and pH-responsiveness, cotton fabrics were fast formed, and the stimuli-responsiveness of the materials was well controlled. In addition, the antimicrobial testing reveals efficient activity of cotton fabrics with the sericin/PNIPAM/PEO nanofiber treatments against Gram-positive bacteria and Gram-negative bacteria such as Staphylococcus aureus and Escherichia coli. The research shows that the presented strategy demonstrated the great potential of multi-function responsive cotton fabrics fabricated using our method.
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静电纺丝胶/ pnipam基纳米改性棉织物的多功能响应性研究
人们对开发环境响应型或刺激响应型智能材料非常感兴趣。本研究的目的是研究纳米级表面改性的多功能反应棉织物。采用静电纺丝技术、互穿聚合物网络技术和交联技术制备了丝胶/聚(n -异丙基丙烯酰胺)/聚(环氧乙烷)多功能纳米纤维,并将其接枝到棉织物表面,使棉织物具有优异的刺激响应功能。通过扫描电镜(SEM)、DSC、ph响应膨胀行为测试和接触角测量来评价复合材料的多功能响应性能。结果表明,该方法能快速形成棉织物的热响应性和ph响应性等多功能响应性,并能很好地控制材料的刺激响应性。此外,抗菌测试表明,丝胶蛋白/PNIPAM/PEO纳米纤维处理棉织物对革兰氏阳性菌和革兰氏阴性菌(如金黄色葡萄球菌和大肠杆菌)具有有效的抗菌活性。研究表明,该策略显示了用我们的方法制造多功能响应棉织物的巨大潜力。
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