Diastereoselective Intramolecular Photochemical [2+2] Cycloaddition Reactions of Tethered L-(+)-Valinol Derived Tetrahydrophthalimides

K. Booker‐Milburn, S. Gulten, Andrew Sharpe
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引用次数: 11

Abstract

Intramolecular photochemical [2 + 2] cycloaddition of allyl alcohol linked to amino acid derived 3,4,5,6-tetrahydrophthalimides, either via a carbonate or silicon tether, gives the corresponding cyclobutanes in excellent yield with diastereoselectivities as high as 8:1.
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系链L-(+)-缬氨酸衍生四氢邻苯二胺的非对映选择性分子内光化学[2+2]环加成反应
分子内光化学[2 + 2]环加成烯丙醇通过碳酸盐或硅系链与氨基酸衍生的3,4,5,6-四氢邻苯二胺相连,得到相应的环丁烷,产率高,非对映选择性高达8:1。
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