Application of the Tammann-Tait-Gibson model to aqueous solvent molar volume isotope effects in electrolyte solutions

W.Alexander Van Hook
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引用次数: 1

Abstract

Solvent isotope effects on apparent and partial molar volumes in rmH2D2O electrolyte solutions are rationalized in terms of the Tammann-Tait-Gibson model using as input information known isotope effects on the compressibility and molar volume of the pure solvents, and results of compressibility measurements on H2O solutions.

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Tammann-Tait-Gibson模型在电解质水溶液摩尔体积同位素效应中的应用
根据Tammann-Tait-Gibson模型,将已知同位素对纯溶剂的可压缩性和摩尔体积的影响以及对H2O溶液的可压缩性测量结果作为输入信息,对溶剂同位素对rmH2D2O电解质溶液的表观和部分摩尔体积的影响进行了合理化。
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