Rheological properties of lithium, lithium complex, and sodium greases

Abstract

The rheological properties of two lithium, two lithium complex, and two sodium greases, all with the most common NLGI grade two, have been investigated. The greases are based on a mineral and a synthetic oil. The apparatus used was a cone-and-plate rheometer and an impacting-ball apparatus. The impacting-ball apparatus used a steel ball, which impacted a lubricated sintered carbide plate, to measure the shear stress-pressure coefficient, γ, of the lubricant. At pressures found in elastohydrodynamic contacts this coefficient determined the limiting shear stress. The γ-value thus affects the coefficient of friction and consequently, lower γ-value means less friction. The results from the impacting-ball apparatus showed that the γ-value was lower for the greases with a synthetic base oil and that the lithium greases gave a lower γ-value than the corresponding base oils. Results from the cone-and-plate rheometer showed the characteristic shear thinning behaviour of the greases and the influence of shear history and temperature. The results from the cone-and-plate rheometer have also been fitted to a four parameter rheological model.