Temperature Dependence of Viscosity and Surface Tension in Zn-Cd Liquid Alloy Using Optimization Method

H. K. Limbu, G. Adhikari
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引用次数: 1

Abstract

We have computed interchange energy by estimating the best fit experimental and theoretical values at 800K using Flory’s model. Taking these values at 800K, interchange energy at different temperatures are calculated using optimization method and with the help of which free energy of mixing, heat of mixing and entropy of mixing are obtained. The partial excess free energy is calculated with the help of values of free energy of mixing which is used to find surface tension. Butler’s equation and Layered structure approach have been used to calculate surface tension of Zn-Cd alloy. Viscosity is obtained from Singh and Sommer’s formulation, Moelwyn-Hughes equation, and Kaptay equation.
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基于优化方法的Zn-Cd液态合金粘度和表面张力温度依赖性研究
我们利用Flory的模型估计了800K时最适合的实验值和理论值,从而计算了交换能。取800K时的这些值,用最优化方法计算了不同温度下的交换能,得到了混合自由能、混合热和混合熵。利用混合自由能的值计算了部分过剩自由能,混合自由能用于计算表面张力。采用巴特勒方程和层状结构法计算了锌镉合金的表面张力。粘度由Singh和Sommer的公式、Moelwyn-Hughes方程和Kaptay方程获得。
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