Mechanical and Heat Shrinkable Properties of Electron Beam Irradiated Polypropylene With Bisphenol A Dimethacrylate Crosslinker

Z. Roja, I. Reinholds, J. Zicans, R. M. Meri
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引用次数: 3

Abstract

Abstract Radiation crosslinking of polyolefins has gained interest for the development of advanced heat-shrinkable materials. Propylene homopolymer (PP1), polypropylene-polyethylene block copolymers (PP2, PP3) and their mixtures with 3 wt.% of bisphenol A dimethacrylate (BPDMA) crosslinking agent were irradiated with 25–150 kGy of accelerated electrons and were compared for aforementioned purpose. The studied mechanical properties indicated increased elongation in the presence of BPDMA that was contributed to the crosslinked moieties of PP and the crosslinking agent. The shrinkage stresses were comparable to that of polyethylene based heat-shrinkable material.
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双酚A二甲基丙烯酸酯交联剂辐照聚丙烯的力学和热收缩性能
聚烯烃的辐射交联已成为开发高级热收缩材料的研究热点。用25-150 kGy的加速电子辐照丙烯均聚物(PP1)、聚丙烯-聚乙烯嵌段共聚物(PP2、PP3)及其与3 wt.%双酚A二甲基丙烯酸酯(BPDMA)交联剂的混合物,并对其进行了比较。研究的力学性能表明,BPDMA的存在增加了伸长率,这是由于PP和交联剂的交联部分。收缩应力与聚乙烯基热收缩材料相当。
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