Thermodynamic Evaluation of Sulfate-Roasting Process for the Vanadium Extraction from Korean VTM Ore

Youngjae Kim, Kyungsob Choi, Hyunsik Park, K. Chung
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引用次数: 2

Abstract

In the present study, the thermodynamic evaluation of the sulfate-roasting process was conducted to extract vanadium from the Korean vanadium titano-magnetite ore. The leaching efficiency of vanadium and other impurities was analyzed for varying roasting temperatures and addition of Na 2 SO 4 . In the case of sulfate roasting, the roasting temperature was 200 ℃ higher than that previously observed Na 2 CO 3 roasting. However, the higher leaching efficiency of vanadium and lower leaching efficiency of other impurities, such as aluminum and silicon, were observed. The high selectivity for the extraction of vanadium in sulfate roasting would result from the reaction mechanism between SO 2 gas and vanadium concentrate.
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韩国VTM矿硫酸盐焙烧提钒工艺热力学评价
对韩国某钒钛磁铁矿进行了硫酸盐焙烧提钒的热力学评价,分析了不同焙烧温度和添加na2so4对钒及其他杂质的浸出效果。在硫酸盐焙烧的情况下,焙烧温度比先前观察到的na2co3焙烧温度高200℃。但钒的浸出效率较高,铝、硅等杂质的浸出效率较低。硫酸焙烧中钒的高选择性是由二氧化硫气体与钒精矿的反应机理决定的。
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