T. Ho, M. Fieser, R. Danheiser, W. Roush, L. Fieser
{"title":"Palladium(II) acetate","authors":"T. Ho, M. Fieser, R. Danheiser, W. Roush, L. Fieser","doi":"10.1002/9780471264194.FOS07552.PUB6","DOIUrl":null,"url":null,"abstract":"This article has no abstract. \n \nKeywords: \n \noxidative dimerization of β-substituted α-olefins; \nbenzylic oxidation of toluenes; \nπ-allylpalladium complexes; \ncyclopropanation; \nsubstitution of vinylic hydrogens; \noxidation of ethylene; \ncyclopropanation; \nexamples; \nArI Ar–Ar; \nacetoxylation of arenes; \narylation of allylic alcohols with aryl halides; \nα,β-enones; \n1,4-dienes; \n(E)- and (Z)-alkenes; \narylation of allylic alcohols; \narylation of olefins; \nterminal 1,3-dienes; \n2,2,7,7,12,13,17,18-octamethylisobacteriochlorin; \nα,β-enones; \nbenzohydrofuranes; \ntransannular reactions of grayanotoxin-II; \ncyclopentenes; \n3-methyl-2-cyclopentenones; \npolycyclic indoles; \nβ-lactams; \nintramolecular cyclization via π-allylpalladium complexes; \nβ-aryl-α,β-unsaturated carbonyl compounds; \narenecarboxylic acids; \n2,2′-bipyrroles; \nbridged and spirocyclic bicycloalkenones; \nketones from halohydrins; \narylation of quinones; \ncyclopropanation; \n1,4-diacetoxylation of1,3-dienes; \n1,4-acetoxytrifluoroacetoxylation of 1,3-dienes; \nvinylation of alkyl or aryl halides; \nβ-aryl aldehydes; \nhydrogenolysis of allylic acetates; \nenones; \northo-alkylation of acetanilides; \narylation of cycloalkenes; \nallylic acetoxylation; \noxidative coupling of alkenylstannanes; \nlactonization of dienes by 1,4-functionation; \n1,3,5-trienes; \ncyclization of o-iodophenyl allyl ethers to benzofurans; \ncoupling of CH2CHSi(CH3)3 with vinyl iodides; \nvinylation of cycloalkenes; \narylannelation of 1,3-dienes; \ncoupling of ArI and unsaturated epoxides; \nbicyclic acetals; \n1,4-additions to1,3-dienes; \ndidehydroamino acids; \ncyclopentenones from carbohydrates; \n3-arylcycloalkenes; \ncoupling of vinyl halides with allylic alcohols; \ncyclization of 4,6- and 5,7-dieneamides; \noxaspirocyclic addition to 1,3-dienes; \nRCH2CHO RCHCHOCH3 RCHCHCHO; \nheck cyclization; \nheck-type coupling of allylic alcohols and enol triflates; \ncoupling of vinyl halides with allyl alcohols; \narylation of allylic alcohols; \nhydroacetoxylation of 2-alkynoates; \nthree-component coupling of alkenes; \nheck reaction; \nsuzuki, stille, and related couplings; \nreductive acylation and transesterification; \n2-benzenesulfenyl-1,3-dienes; \nallylic oxidation; \n1,4-difunctionalization of 1,3-dienes; \ncycloisomerization of enynes; \nheck reaction; \narylation with onium salts; \nsuzuki couplings; \ncarboxylation; \naddition to multiple bonds; \noxidation; \nheck reaction and other couplings; \naddition to multiple bonds; \ndehydrogenation of carbonyl compounds; \nindoles; \ncyclopropanation; \nenol ethers; \ncoupling reactions; \nreactions of alkynes; \ncarbonyl compounds; \nmiscellaneous reactions; \nhydroarylation; \ncarboxylation; \nrearrangement-coupling; \nconjugate addition; \ncoupling reactions; \nredox reactions; \nvinyl glycosides; \ncyclizations; \nadditions; \nallylic displacements; \ncyclopropanation; \ncoupling reactions; \naddition reactions; \ncyclization reactions; \ncyclopentadienone acetals; \noxidation; \nketone synthesis; \nracemization; \ntransannular reaction; \ncoupling reactions; \noxidation; \naryl ketones; \nreaction with ArNCl2; \nhalogenation; \nreduction; \ncoupling reactions; \ncyclization; \nhalogenation","PeriodicalId":12135,"journal":{"name":"Fieser and Fieser's Reagents for Organic Synthesis","volume":"15 1","pages":"000-000"},"PeriodicalIF":0.0000,"publicationDate":"2017-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fieser and Fieser's Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780471264194.FOS07552.PUB6","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
This article has no abstract.
Keywords:
oxidative dimerization of β-substituted α-olefins;
benzylic oxidation of toluenes;
π-allylpalladium complexes;
cyclopropanation;
substitution of vinylic hydrogens;
oxidation of ethylene;
cyclopropanation;
examples;
ArI Ar–Ar;
acetoxylation of arenes;
arylation of allylic alcohols with aryl halides;
α,β-enones;
1,4-dienes;
(E)- and (Z)-alkenes;
arylation of allylic alcohols;
arylation of olefins;
terminal 1,3-dienes;
2,2,7,7,12,13,17,18-octamethylisobacteriochlorin;
α,β-enones;
benzohydrofuranes;
transannular reactions of grayanotoxin-II;
cyclopentenes;
3-methyl-2-cyclopentenones;
polycyclic indoles;
β-lactams;
intramolecular cyclization via π-allylpalladium complexes;
β-aryl-α,β-unsaturated carbonyl compounds;
arenecarboxylic acids;
2,2′-bipyrroles;
bridged and spirocyclic bicycloalkenones;
ketones from halohydrins;
arylation of quinones;
cyclopropanation;
1,4-diacetoxylation of1,3-dienes;
1,4-acetoxytrifluoroacetoxylation of 1,3-dienes;
vinylation of alkyl or aryl halides;
β-aryl aldehydes;
hydrogenolysis of allylic acetates;
enones;
ortho-alkylation of acetanilides;
arylation of cycloalkenes;
allylic acetoxylation;
oxidative coupling of alkenylstannanes;
lactonization of dienes by 1,4-functionation;
1,3,5-trienes;
cyclization of o-iodophenyl allyl ethers to benzofurans;
coupling of CH2CHSi(CH3)3 with vinyl iodides;
vinylation of cycloalkenes;
arylannelation of 1,3-dienes;
coupling of ArI and unsaturated epoxides;
bicyclic acetals;
1,4-additions to1,3-dienes;
didehydroamino acids;
cyclopentenones from carbohydrates;
3-arylcycloalkenes;
coupling of vinyl halides with allylic alcohols;
cyclization of 4,6- and 5,7-dieneamides;
oxaspirocyclic addition to 1,3-dienes;
RCH2CHO RCHCHOCH3 RCHCHCHO;
heck cyclization;
heck-type coupling of allylic alcohols and enol triflates;
coupling of vinyl halides with allyl alcohols;
arylation of allylic alcohols;
hydroacetoxylation of 2-alkynoates;
three-component coupling of alkenes;
heck reaction;
suzuki, stille, and related couplings;
reductive acylation and transesterification;
2-benzenesulfenyl-1,3-dienes;
allylic oxidation;
1,4-difunctionalization of 1,3-dienes;
cycloisomerization of enynes;
heck reaction;
arylation with onium salts;
suzuki couplings;
carboxylation;
addition to multiple bonds;
oxidation;
heck reaction and other couplings;
addition to multiple bonds;
dehydrogenation of carbonyl compounds;
indoles;
cyclopropanation;
enol ethers;
coupling reactions;
reactions of alkynes;
carbonyl compounds;
miscellaneous reactions;
hydroarylation;
carboxylation;
rearrangement-coupling;
conjugate addition;
coupling reactions;
redox reactions;
vinyl glycosides;
cyclizations;
additions;
allylic displacements;
cyclopropanation;
coupling reactions;
addition reactions;
cyclization reactions;
cyclopentadienone acetals;
oxidation;
ketone synthesis;
racemization;
transannular reaction;
coupling reactions;
oxidation;
aryl ketones;
reaction with ArNCl2;
halogenation;
reduction;
coupling reactions;
cyclization;
halogenation
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