On many-electron effects and multiplet splittings in X-ray photoelectron spectroscopy as a diagnostic tool for metallic glasses

Z.M. Stadnik , J.F. Van Acker, J.C. Fuggle, H.J.W.M. Hoekstra, K.H.J. Buschow, T. Miyazaki, G. Stroink
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引用次数: 1

Abstract

(Ni1−xFex)77Si10B13 glasses and crystalline iron, nickel, Fe2Gd and Fe2Ti were studied with X-ray photoelectron spectroscopy. It is shown that characteristics of Ni 2p32 satellites are sensitive to changes in the glass composition. It is found that the Fe 3s multiplet splitting, both in glasses and crystalline alloys, does not scale with the iron magnetic moment.

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作为金属玻璃诊断工具的x射线光电子能谱中的多电子效应和多重分裂
用x射线光电子能谱研究了(Ni1−xFex)77Si10B13玻璃和结晶铁、镍、Fe2Gd和Fe2Ti。结果表明,Ni 2p32卫星的特性对玻璃组分的变化非常敏感。结果表明,无论是在玻璃中还是在结晶合金中,fe3s多晶分裂都不随铁磁矩成比例。
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