{"title":"Partial synthesis of mexicanolide from 7-oxo-7-deacetoxykhivorin","authors":"J. D. Connolly, Ian M. S. Thornton, D. Taylor","doi":"10.1039/C29710000017","DOIUrl":null,"url":null,"abstract":"7-Oxo-7-deacetoxykhivorin has been transformed into the diene-lactone (XI), a postulated biogenetic precursor of the bicyclonanolide group of tetranortriterpenoids, which when treated with very mild base readily undergoes intramolecular Michael addition to give mexicanolide (XII).","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"23 1","pages":"17-18"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710000017","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
Abstract
7-Oxo-7-deacetoxykhivorin has been transformed into the diene-lactone (XI), a postulated biogenetic precursor of the bicyclonanolide group of tetranortriterpenoids, which when treated with very mild base readily undergoes intramolecular Michael addition to give mexicanolide (XII).
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