Zinc(II) Complex of Meso-Tetraphenylporphyrin With 4-Methoxyaniline: Crystal Structure and Antimicrobial Activities of 4-Methoxyaniline-5, 10, 15, 20-Tetraphenyl-Porphyrinatozinc (II)

J. Obaleye, A. Tella, G. K. Obiyenwa, Nzikahyel Simon, M. D. Olawale
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引用次数: 4

Abstract

4-Methoxyaniline-5,10,15,20-tetraphenylporphyrinatozinc(II), [(ZnTPP(MOAN)] 1 was synthesized (MOAN = 4-methoxyaniline) and characterized by elemental analysis and spectroscopic techniques. The molecular structure of 1 was determined by single-crystal X-ray crystallography. The structure revealed a triclinic crystal system and the space group P1 with the central metal adopting slightly distorted square pyramidal geometry with 4-methoxyaniline in the axial position. The antimicrobial activities were carried out using a well diffusion method and the zone of inhibition of four bacteria and two fungi was measured.
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4-甲氧基苯胺- 5,10,15,20 -四苯基卟啉锌(II)配合物的晶体结构及抗菌活性
合成了4-甲氧基苯胺-5,10,15,20-四苯基卟啉锌(II), [(ZnTPP(MOAN)] 1 (MOAN = 4-甲氧基苯胺),并用元素分析和光谱技术对其进行了表征。用单晶x射线晶体学测定了1的分子结构。结构为三斜晶系和空间群P1,中心金属呈轻微畸变的方锥体几何形状,4-甲氧基苯胺在轴向位置。采用孔扩散法测定其抑菌活性,并测定其对4种细菌和2种真菌的抑菌区。
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