The integrated absorption intensity of the CO stretching bands of normal and 15N-barbituric acid

S. Pinchas
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引用次数: 10

Abstract

The integrated absorption intensity of the CO stretching bands of 99 % 15N-barbituric acid dissolved in dimethylsulphoxide was measured in comparison with that of the CO bands of normal barbituric acid and was found to be practically the same in both cases.

The origin of the different CO bands of barbituric acid is discussed on basis of the observed 15N-isotope shifts of these bands. The assignment of other bands observed for the solution of this acid is suggested.

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正常巴比妥酸和15n巴比妥酸的CO拉伸带的综合吸收强度
测定了99% 15n -巴比妥酸在二甲亚砜中的CO拉伸带的综合吸收强度,并与正常巴比妥酸的CO拉伸带的综合吸收强度进行了比较,发现两种情况下CO拉伸带的综合吸收强度几乎相同。根据巴比妥酸不同CO谱带的15n同位素位移,讨论了这些谱带的来源。对该酸溶液中观察到的其他谱带的分配提出了建议。
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