Y. Yamano, Yasuko Watanabe, N. Watanabe, Masayoshi Ito
{"title":"Stereocontrolled synthesis of glucosidic damascenone precursors","authors":"Y. Yamano, Yasuko Watanabe, N. Watanabe, Masayoshi Ito","doi":"10.1039/B208758H","DOIUrl":null,"url":null,"abstract":"A stereocontrolled synthesis of optically active β-D-glucopyranosides 7–10 and 11–14, glucosidic damascenone precursors, was accomplished utilizing an asymmetric transfer hydrogenation to α,β-acetylenic ketones catalyzed by chiral ruthenium complexes as the key step.","PeriodicalId":17267,"journal":{"name":"Journal of The Chemical Society-perkin Transactions 1","volume":"14 1","pages":"2833-2844"},"PeriodicalIF":0.0000,"publicationDate":"2002-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"19","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society-perkin Transactions 1","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/B208758H","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 19
Abstract
A stereocontrolled synthesis of optically active β-D-glucopyranosides 7–10 and 11–14, glucosidic damascenone precursors, was accomplished utilizing an asymmetric transfer hydrogenation to α,β-acetylenic ketones catalyzed by chiral ruthenium complexes as the key step.