O. Şahin, O. Büyükgüngör, D. A. Köse, B. Zümreoğlu-Karan
{"title":"Synthesis and Crystal Structure of Tetraquaorotatonickel(II) Monohydrate","authors":"O. Şahin, O. Büyükgüngör, D. A. Köse, B. Zümreoğlu-Karan","doi":"10.2116/ANALSCIX.24.X211","DOIUrl":null,"url":null,"abstract":"The title compound, tetraquaorotatonickel(II) monohydrate, C5H12N2O9Ni, crystallizes in the monoclinic space group P1 with the following unit-cell parameters: a = 7.2282(4)A, b = 8.2959(4)A, c = 10.0611(5)A, α = 80.115(4)°, β = 70.479(4)°, γ = 65.779(4)° and Z = 2. The NiII ion is coordinated by a deprotonated N atom and the carboxylate O atom of the orotate ligand and four aqua ligands in a distorted octahedral geometry. Intermolecular N-H…O and O-H…O hydrogen bonds produce R22(8), R22(12), R22(16), R32(8), R43(8) and R44(12) rings, which lead to a one-dimensional polymeric chains. An extensive three-dimensional network of N-H…O and O-H…O hydrogen bonds, π-π and N-H…π interactions are responsible for crystal stabilization.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"76 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X211","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The title compound, tetraquaorotatonickel(II) monohydrate, C5H12N2O9Ni, crystallizes in the monoclinic space group P1 with the following unit-cell parameters: a = 7.2282(4)A, b = 8.2959(4)A, c = 10.0611(5)A, α = 80.115(4)°, β = 70.479(4)°, γ = 65.779(4)° and Z = 2. The NiII ion is coordinated by a deprotonated N atom and the carboxylate O atom of the orotate ligand and four aqua ligands in a distorted octahedral geometry. Intermolecular N-H…O and O-H…O hydrogen bonds produce R22(8), R22(12), R22(16), R32(8), R43(8) and R44(12) rings, which lead to a one-dimensional polymeric chains. An extensive three-dimensional network of N-H…O and O-H…O hydrogen bonds, π-π and N-H…π interactions are responsible for crystal stabilization.