A STUDY ON ENHANCING THE FLAME RETARDANCY OF POLYPROPYLENE YARN WITH BORON COMPOUNDS

E. Eskiyapar, H. K. Kaynak, H. Çelik, E. Sarıoğlu
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Abstract

Functional properties such as; water resistance, flame retardancy, antibacterial efficiency etc. are required from textile products. One of the most commonly demanded products among functional textile products is the flame-retardant textiles. In this study, it is aimed to produce polypropylene filament yarn with permanent flame retardancy functionality by adding boron compound, which is Anhydrous disodium tetraborate powder (particle size < 38 micron), to the fiber structure during melt spinning process. In this study two different yarn samples are produced with anhydrous disodium tetraborate content by mass ratios of 2% and 5%. A control polypropylene filament yarn sample is also produced with no additive. By this way, three samples are produced by a conventional BCF polypropylene melt spinning machine with the same production parameters. Then, three knitted fabric samples were produced flat knitting machine. Limiting Oxygen Index (LOI) and vertical flammability tests were applied to the samples. According to results an important level of increase for LOI value is obtained with the sample which has 2% boron compound additive. Nevertheless, there is not a consistent effect of increasing boron content in yarn structure for LOI value. The reason of this situation may be resulted due to the uneven distribution of the boron compound in the yarn structure because of the particle size.
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硼化合物增强聚丙烯丝阻燃性能的研究
功能特性如;纺织产品的耐水性、阻燃性、抗菌效率等要求。阻燃纺织品是功能性纺织品中需求量最大的产品之一。本研究的目的是在熔融纺丝过程中,在纤维结构中加入硼化合物,即无水二钠四硼酸盐粉末(粒径< 38微米),以生产具有永久阻燃功能的聚丙烯长丝。在本研究中,用质量比为2%和5%的无水四硼酸二钠生产了两种不同的纱线样品。在不添加添加剂的情况下,还生产了对照聚丙烯长丝样品。通过这种方法,在相同的生产参数下,在传统的BCF聚丙烯熔体纺纱机上生产了3个样品。然后,用横机生产了三种针织物样品。对样品进行了极限氧指数(LOI)和垂直可燃性测试。结果表明,添加2%硼的复合添加剂对样品的LOI值有较大的提高。然而,纱线结构中硼含量的增加对LOI值的影响并不一致。造成这种情况的原因可能是由于硼化合物在纱线结构中的分布不均匀。
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