Susana M. M. Lopes, Sandra C. C. Nunes, Catia C. Caratao, Alberto A. C. C. Pais, Teresa M. V. D. Pinho e Melo
{"title":"ChemInform Abstract: Reactivity of 1-Arylnitrosoethylenes Towards Indole Derivatives.","authors":"Susana M. M. Lopes, Sandra C. C. Nunes, Catia C. Caratao, Alberto A. C. C. Pais, Teresa M. V. D. Pinho e Melo","doi":"10.1002/chin.201652221","DOIUrl":null,"url":null,"abstract":"<p>Indole (II) and 1-methylindole (VII) react with 1-arylnitrosoethylene leading to intermediate hetero-Diels—Alder cycloadducts, which suffer an 1,2-oxazine ring-opening reaction to form 3-alkylated indoles.</p>","PeriodicalId":9834,"journal":{"name":"ChemInform","volume":"47 52","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2016-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/chin.201652221","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemInform","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/chin.201652221","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
Indole (II) and 1-methylindole (VII) react with 1-arylnitrosoethylene leading to intermediate hetero-Diels—Alder cycloadducts, which suffer an 1,2-oxazine ring-opening reaction to form 3-alkylated indoles.