Sepiolites as supports for Pd catalysts used in organic reduction processes

Q4 Chemical Engineering 分子催化 Pub Date : 1994-11-13 DOI:10.1016/0304-5102(94)87034-9
M.A. Aramendía, V. Borau, C. Jiménez, J.M. Marinas, A. Porras, F.J. Urbano, L. Villar
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引用次数: 18

Abstract

This paper reviews the use of Spanish sepiolites as supports for Pd catalysts employed for the reduction of variously substituted alkenes, the selective semi-hydrogenation of phenylacetylene and the reduction of acetophenone, both with gaseous hydrogen and by hydrogen transfer with cyclohexene as donor. The performance of Pd/sepiolite catalysts is compared with that of synthesized catalysts supported over SiO2, SiO2AlPO4, AlPO4 and AlPO4Al2O3, which we have used extensively, as well as with that of several commercially available catalysts from Fluka, Merck and Degussa.

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海泡石作为有机还原过程中钯催化剂的载体
本文综述了以西班牙海泡石为载体的钯催化剂在以气态氢和以环己烯为供体的氢转移还原各种取代烯烃、苯乙炔选择性半加氢和苯乙酮还原中的应用。将Pd/海泡石催化剂的性能与我们广泛使用的SiO2、SiO2AlPO4、AlPO4和AlPO4Al2O3负载的合成催化剂的性能以及Fluka、Merck和Degussa的几种市售催化剂的性能进行了比较。
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来源期刊
分子催化
分子催化 Chemical Engineering-Catalysis
CiteScore
1.50
自引率
0.00%
发文量
2959
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Author index Subject index Hydrolysis of sucrose by dealuminated Y-zeolites Synthesis and application of organophilic polystyrene-montmorillonite supported onium salts in organic reactions Effect of the reduction temperature on the selectivity of the high temperature reaction of acetone and hydrogen over alumina and titania supported nickel and cobalt catalysts
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