Effects of gamma-radiation on the polymer electrolyte P(EO)8·LiClO4

P. Ferloni , A. Magistris, G. Chiodelli , A. Faucitano , A. Buttafava
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引用次数: 1

Abstract

The polymer electrolyte formed with poly(ethylene oxide), P(EO) and LiClO4 in the n = 8:1 ratio (n = [EO units]/[Li]) was exposed to γ-radiation at room temperature in aqueous solution, then dried and characterized using thermal and conductivity measurements. Its improved electrical and mechanical properties, in comparison with those of the non-irradiated material, suggest that cross-linked P(EO)8·LiClO4 can advantageously replace the usual polymer electrolyte of the same composition in electrochemical devices in the solid state.

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γ辐射对聚合物电解质P(EO)8·LiClO4的影响
将聚(环氧乙烷)、P(EO)和LiClO4按n = 8:1的比例(n = [EO单位]/[Li])形成的聚合物电解质暴露于室温下的水溶液中,然后干燥,用热导率测量对其进行表征。与未辐照材料相比,交联P(EO)8·LiClO4的电学和力学性能得到了改善,这表明交联P(EO)8·LiClO4可以在固态状态下取代电化学器件中相同成分的常用聚合物电解质。
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Corrigendum Erratum Announcement Measurement of radiation damage on organic scintillators caused by gamma-rays and its recovery time Radiation effects on crystalline polymers—I. Gamma-radiation-induced crosslinking and structural characterization of polyethylene oxide
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