Photocatalytic decolorization of methyl orange dye using SnO2-TiO2 nanocomposite particles synthesised by Ultrasonic Assisted Co-Precipitation Method

M. A. S. Azad, Newaz Muhammed Bahadur, Md. Shahadat Hossain, A. Masum
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Abstract

The ultrasonic-aided co-precipitation method was used to create SnO2-TiO2 nanocomposite particles. Scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and UV-vis spectroscopy were used to characterize the nanocomposite particles. XRD patterns revealed the crystalline structure of particles and the average particle size determined by Debye Scherrer’s equation was found to be 11.355, 4.9577, and 4.333 nm for TiO2 nanoparticles, SnO2 nanoparticles, and SnO2-TiO2 nanocomposites, respectively. The Ti, Sn, and O species were confirmed to exist by energy-dispersive X-ray spectroscopy (EDS). The UV absorption peaks at 288, 305, and 350 nm were attributed to SnO2, TiO2-SnO2, and TiO2 respectively. The photocatalytic aspect was investigated in a model organic contaminant (methyl orange). Data obtained by the above-mentioned characterization methods confirmed the superior photocatalytic activity of SnO2-TiO2 nanostructure than SnO2 or TiO2 alone.
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超声辅助共沉淀法合成SnO2-TiO2纳米复合粒子光催化甲基橙染料脱色
采用超声辅助共沉淀法制备了SnO2-TiO2纳米复合粒子。利用扫描电镜(SEM)、x射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)和紫外可见光谱(UV-vis)对纳米复合粒子进行了表征。XRD谱图显示了颗粒的晶体结构,通过Debye Scherrer方程确定的TiO2纳米粒子、SnO2纳米粒子和SnO2-TiO2纳米复合材料的平均粒径分别为11.355 nm、4.9577 nm和4.333 nm。通过能谱分析(EDS)证实了Ti、Sn和O的存在。SnO2、TiO2-SnO2和TiO2的紫外吸收峰分别位于288nm、305nm和350nm处。研究了甲基橙在模拟有机污染物中的光催化作用。通过上述表征方法获得的数据证实,SnO2-TiO2纳米结构的光催化活性优于单独的SnO2或TiO2。
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