Is the most stable gas-phase isomer of the benzenium cation a face-protonated π-complex?

M. Glukhovtsev, A. Pross, A. Nicolaides, L. Radom
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引用次数: 25

Abstract

The recent suggestion, based on gas-phase experimental data, that the most stable isomer of protonated benzene has a face-protonated π-complex structure is not supported by our detailed computations which indicate that the π-complex is a second-order saddle point on the potential energy surface, lying 199 kJ mo–1 higher in energy than the well-established C2vσ-protonated structure.
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苯阳离子最稳定的气相异构体是面质子化的π配合物吗?
最近基于气相实验数据提出的质子化苯最稳定的同分异构体具有面质子化π-配合物结构的观点,并没有得到我们详细计算的支持,π-配合物是势能面上的一个二阶鞍点,其能量比已知的c2vσ -质子化结构高199 kJ mo-1。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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