Plasmonic Scattering and Coupling Effects of Indium Nanoparticles Sheets Embedded in SiO2 AR-Coating on Performance Enhancement of Silicon Solar Cells

W. Ho, Hsi-Wen Hsu, Hao-Yu Yang, Jheng-Jie Liu, Yu-Tsen Tsai, Wei-chih Chiu
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Abstract

In this work, performances of silicon solar cells enhancing by plasmonic scattering and coupling of two-dimensional (2-D) indium nanoparticles (In-NPs) sheets (1-3 layers) embedded in SiO2 antireflective coating (ARC) were demonstrated. Raman and absorbance measurements were examined the plasmonic scattering and coupling effects of 2-D In-NPs sheets embedded in SiO2 layer. Optical reflectance and external quantum efficiency were used to characterize the benefit of plasmonic ARC due to with 2-D In-NPs sheets embedded in SiO2. Photovoltaic current density-voltage measurements under AM 1.5G illumination were used to confirm the enhancement of short-circuit current density and conversion efficiency of the silicon solar cells coated with plasmonic ARC which was depended on In-NPs sheets number. Impressive efficiency enhancements of 39.57%, 38.59%, 34.27% for the cells with 3-, 2-, 1-In NPs sheets embedded in SiO2 layer and of 27.13% for the cell with a SiO2 layer without In-NPs sheet were obtained, respectively, compared to the reference cell.
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SiO2 ar涂层中嵌入铟纳米粒子片的等离子体散射和耦合效应对硅太阳电池性能的增强
在这项工作中,通过等离子体散射和嵌入SiO2抗反射涂层(ARC)的二维(2-D)铟纳米颗粒(In- nps)片(1-3层)的耦合,证明了硅太阳能电池的性能。利用拉曼光谱和吸光度测量方法研究了嵌入SiO2层的二维in - nps片的等离子体散射和耦合效应。利用光学反射率和外量子效率来表征在SiO2中嵌入二维in - nps片所带来的等离子弧效应。通过在AM 1.5G光照下的光伏电流密度-电压测量,证实了等离子弧涂层对硅太阳电池的短路电流密度和转换效率的提高与In-NPs片数有关。与对照电池相比,在SiO2层中嵌入3-、2-、1-In NPs片的电池效率分别提高了39.57%、38.59%和34.27%,而在SiO2层中不嵌入in -NPs片的电池效率分别提高了27.13%。
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