OPTIMIZATION OF BIODIESEL PRODUCTION THROUGH BASE-CATALYZED METHANOLYSIS OF CANTALOUPE SEED OIL

T. Akhtar
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Abstract

Biodiesel represents a suitable alternative to the petroleum-derived diesel fuel as it is renewable and can be used directly in compression-ignition engines. Present work was aimed at extraction of cantaloupe seed oil and its application to the production of biodiesel through base- catalyzed transesterification using four different basic catalysts viz. NaOH, NaOCH3, KOH and KOCH3. The percent yield of biodiesel afforded by these catalysts was 94.5, 88.0, 85.5 and 89.5%, respectively. The results indicated that NaOH was the best catalyst for transesterification of cantaloupe seed oil. Further, optimization of the process variable, including methanol to oil mole ratio, reaction temperature and amount of catalyst (NaOH) was carried out. The optimum levels of these variables that afforded maximum biodiesel yield were found to be 6:1 molar ratio of methanol to oil, 60 oC reaction temperature and one percent wt/wt catalyst loading. From the results obtained in this study,it was concluded that cantaloupe seed oil can be successfully utilized for the production of biodiesel as a cost-effective feedstock.
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哈密瓜籽油碱催化甲醇裂解生产生物柴油的优化研究
生物柴油是石油衍生柴油的合适替代品,因为它是可再生的,可以直接用于压缩点火发动机。研究了在NaOH、NaOCH3、KOH和KOCH3四种碱性催化剂的催化下,哈密瓜籽油的提取及其在生物柴油生产中的应用。这些催化剂的生物柴油收率分别为94.5%、88.0、85.5%和89.5%。结果表明,氢氧化钠是哈密瓜籽油酯交换反应的最佳催化剂。进一步对甲醇油摩尔比、反应温度、催化剂(NaOH)用量等工艺参数进行了优化。这些变量的最佳水平为甲醇与油的摩尔比为6:1,反应温度为60℃,催化剂的重量比为1%,可获得最大的生物柴油产量。从本研究的结果来看,哈密瓜籽油可以作为一种经济有效的原料成功地用于生产生物柴油。
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