{"title":"Tris(trimethylsilyl)silane","authors":"B. Giese, J. Dickhaut, C. Chatgilialoglu","doi":"10.1002/9780470842898.RT420.PUB2","DOIUrl":null,"url":null,"abstract":"[1873-77-4] C9H28Si4 (MW 248.73) \n \n \n \n \n \nInChI = 1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3 \n \n \n \nInChIKey = SQMFULTZZQBFBM-UHFFFAOYSA-N \n \n \n \n(mediator of radical reactions;1, 2 nontoxic substitute for tri-n-butylstannane in radical reactions; slower hydrogen donor than tri-n-butylstannane3) \n \n \n \nAlternatives names: TTmss(Tms)3SiH \n \n \n \nPhysical Data: bp 82–84 °C/12 mmHg; d 0.806 g cm−3; n20D 1.489. \n \n \n \nSolubility: sol pentane, ether, toluene, THF; modestly sol acetone, acetonitrile; insol H2O; decomposes rapidly in methanol and other alcohols. \n \n \n \nForm Supplied in: colorless liquid; commercially available. \n \n \n \nPreparative Method: easy to synthesize.4 \n \n \n \nHandling, Storage, and Precautions: is slightly sensitive to oxygen and should be stored under nitrogen.5 It showed no toxicity in several biological test systems.6","PeriodicalId":11669,"journal":{"name":"Encyclopedia of Reagents for Organic Synthesis","volume":"56 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2003-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Encyclopedia of Reagents for Organic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780470842898.RT420.PUB2","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
[1873-77-4] C9H28Si4 (MW 248.73)
InChI = 1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3
InChIKey = SQMFULTZZQBFBM-UHFFFAOYSA-N
(mediator of radical reactions;1, 2 nontoxic substitute for tri-n-butylstannane in radical reactions; slower hydrogen donor than tri-n-butylstannane3)
Alternatives names: TTmss(Tms)3SiH
Physical Data: bp 82–84 °C/12 mmHg; d 0.806 g cm−3; n20D 1.489.
Solubility: sol pentane, ether, toluene, THF; modestly sol acetone, acetonitrile; insol H2O; decomposes rapidly in methanol and other alcohols.
Form Supplied in: colorless liquid; commercially available.
Preparative Method: easy to synthesize.4
Handling, Storage, and Precautions: is slightly sensitive to oxygen and should be stored under nitrogen.5 It showed no toxicity in several biological test systems.6
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