{"title":"Crystal Structure of the Salen Cobalt(III) Azido Complex Na[Co(salen)(N3)2]","authors":"M. Weil, A. D. Khalaji","doi":"10.2116/ANALSCIX.24.X19","DOIUrl":null,"url":null,"abstract":"The cobalt(III) azido complex, Na[Co(salen)(N3)2], contains a Co(III) cation in a distorted octahedral coordination. The equatorial plane of the octahedron is defined by two N and two O atoms from the tetradentate salen ligand, and the axial ligands belong to two terminal N atoms from two different azide anions. Via interactions between the Na+ cations and the N and O atoms of the ligands, the [Co(salen)(N3)2]- anions are connected into a polymeric structure, forming corrugated ribbons parallel to [100].","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"15 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X19","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5
Abstract
The cobalt(III) azido complex, Na[Co(salen)(N3)2], contains a Co(III) cation in a distorted octahedral coordination. The equatorial plane of the octahedron is defined by two N and two O atoms from the tetradentate salen ligand, and the axial ligands belong to two terminal N atoms from two different azide anions. Via interactions between the Na+ cations and the N and O atoms of the ligands, the [Co(salen)(N3)2]- anions are connected into a polymeric structure, forming corrugated ribbons parallel to [100].