{"title":"A multinuclear NMR study of phosphine coordination complexes of phosphito-P-mercury compounds","authors":"Johann Eichbichler, Paul Peringer","doi":"10.1016/0020-1650(81)80080-3","DOIUrl":null,"url":null,"abstract":"<div><p>At low temperatures (EtO)<sub>2</sub>P(O)HgY (Y = OAc,O<sub>3</sub>SCF<sub>3</sub>,Cl,Br,I,S<sub>2</sub>CNEt<sub>2</sub>,S<sub>2</sub>P(OEt)<sub>2</sub>, 2,5-pyrrolidinedionato-N, and (EtO)<sub>2</sub>P(O)) form coordination compounds (EtO)<sub>2</sub>P(O)c HgY(PR<sub>3</sub>)<sub>n</sub> (R = n-Bu, Ph; n = 1–3 depending on Y); <sup>31</sup>P and <sup>199</sup>Hg NMR data are reported.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80080-3","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800803","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
At low temperatures (EtO)2P(O)HgY (Y = OAc,O3SCF3,Cl,Br,I,S2CNEt2,S2P(OEt)2, 2,5-pyrrolidinedionato-N, and (EtO)2P(O)) form coordination compounds (EtO)2P(O)c HgY(PR3)n (R = n-Bu, Ph; n = 1–3 depending on Y); 31P and 199Hg NMR data are reported.
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