A Study on the Shape Control of Multiple Layers for PES Nanofiber Using Electrospinning Method of Top-down Spinning

Nam-su Kwak, C. Choi, Jeong-Gi Lee
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Abstract

In this study, we investigated the diameter and pore control of PES nanofibers by focusing on the process parameters such as concentration of polymer solution, applied voltage of spin column, and injection rate of polymer solution among various electrospinning parameters. The device for electrospinning was designed by modularizing to be able to cope with changes in test conditions and large area. The detailed device consists of a fabric feeding part, a spinning part, a soaking part, a drying part, and a fabric transfer part, the spinning device is based on top-down spinning and the spinning column is composed of 12 columns with 10 nozzles per column. The results obtained from this study are as follows. The maximum pore diameter is less than 22 kV at an applied voltage of 20 kV, the standard deviation of nanofiber diameter at each applied voltage means that the fibers radiated at 20 kV from 18 kV to 245.84 nm, 20 kV at 183.52, and 22 kV at 232 kV were more uniformly emitted, it has been proved that the nanofibers are radiated unevenly due to the effect of the strong applied voltage at 22 kV.
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静电纺丝法对PES纳米纤维多层形状控制的研究
在本研究中,我们重点研究了不同静电纺丝参数中聚合物溶液浓度、自旋柱施加电压、聚合物溶液注入速度等工艺参数对PES纳米纤维直径和孔隙的控制。静电纺丝装置采用模块化设计,以适应试验条件的变化和试验面积的增大。该装置由织物进料部分、纺纱部分、浸泡部分、干燥部分和织物转移部分组成,纺纱装置采用自上而下纺纱,纺纱柱由12个柱组成,每柱10个喷嘴。本研究的结果如下:施加电压为20 kV时,纳米纤维的最大孔径小于22 kV,各施加电压下纳米纤维直径的标准差表明,在18 ~ 245.84 nm、183.52 nm和232 kV时,20 kV辐射的光纤发射更加均匀,证明了由于22 kV强施加电压的影响,纳米纤维的辐射不均匀。
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