Chen Fengying, W. Shumin, L. Ping, Jing Zhenguo, Zhou Chunsheng
{"title":"Synthesis, Crystal Structure of a 2-D Copper (II) Complex Based on Mixed Organic Ligands","authors":"Chen Fengying, W. Shumin, L. Ping, Jing Zhenguo, Zhou Chunsheng","doi":"10.1080/15533174.2012.760596","DOIUrl":null,"url":null,"abstract":"A novel copper (II) ternary complex with the formula [Cu (HL) (Py) (H2O)] (H3L˭N-(2-Propionic Acid)-salicyloyl hydrazone, Py = pyridine) has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The Cu atom in the complex is five-coordinated by one N and two O atoms of HL and one N atom from pyridine, these four atoms are located at the bottom of the square-pyramid, the other coordinating atom is O atom of H2O locating at the apical position. Intermolecular hydrogen bonds link the complex to form a 2D super molecule network.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":"100 1","pages":"1334 - 1337"},"PeriodicalIF":0.0000,"publicationDate":"2013-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2012.760596","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
A novel copper (II) ternary complex with the formula [Cu (HL) (Py) (H2O)] (H3L˭N-(2-Propionic Acid)-salicyloyl hydrazone, Py = pyridine) has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The Cu atom in the complex is five-coordinated by one N and two O atoms of HL and one N atom from pyridine, these four atoms are located at the bottom of the square-pyramid, the other coordinating atom is O atom of H2O locating at the apical position. Intermolecular hydrogen bonds link the complex to form a 2D super molecule network.