T. Oshikawa,, M. Yamashita,, Sadaaki Kumagai, K. Seo, J. Kobayashi
{"title":"Optically active diazacyclophosphamides: novel efficient reagents for the determination of the absolute configuration of amines and alcohols","authors":"T. Oshikawa,, M. Yamashita,, Sadaaki Kumagai, K. Seo, J. Kobayashi","doi":"10.1039/C39950000435","DOIUrl":null,"url":null,"abstract":"Various amines and alcohols are converted into the corresponding phosphamides by the action of optically active diazacyclophosphamidic chlorides and absolute configurations of amines and alcohols are readily determined by proton and phosphorus NMR of the cyclophosphamides that are formed.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"49 1","pages":"435-436"},"PeriodicalIF":0.0000,"publicationDate":"1995-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"12","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950000435","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 12
Abstract
Various amines and alcohols are converted into the corresponding phosphamides by the action of optically active diazacyclophosphamidic chlorides and absolute configurations of amines and alcohols are readily determined by proton and phosphorus NMR of the cyclophosphamides that are formed.