Спектры комбинационного рассеяния поликристаллических сульфатов лития, натрия и калия в предпереходной температурной области ниже структурного фазового перехода
{"title":"Спектры комбинационного рассеяния поликристаллических сульфатов лития, натрия и калия в предпереходной температурной области ниже структурного фазового перехода","authors":"Араз Рафиг оглы Алиев, И.Р. Ахмедов, М.Г. Какагасанов, З.А. Алиев","doi":"10.21883/FTT.2019.08.47980.382","DOIUrl":null,"url":null,"abstract":"Molecular relaxation processes in lithium sulfate (Li2SO4), sodium sulfate (Na2SO4) and potassium sulfate (K2SO4) were studied by Raman spectroscopy. A decrease in the order parameter in the low-temperature phase is observed when approaching a phase transition, which, for example, is typical of a first-order phase transition close to the second. The existence of the pretransition region in the studied sulfates Li2SO4, Na2SO4 and K2SO4 was found.","PeriodicalId":24077,"journal":{"name":"Физика твердого тела","volume":"14 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Физика твердого тела","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21883/FTT.2019.08.47980.382","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
Molecular relaxation processes in lithium sulfate (Li2SO4), sodium sulfate (Na2SO4) and potassium sulfate (K2SO4) were studied by Raman spectroscopy. A decrease in the order parameter in the low-temperature phase is observed when approaching a phase transition, which, for example, is typical of a first-order phase transition close to the second. The existence of the pretransition region in the studied sulfates Li2SO4, Na2SO4 and K2SO4 was found.