{"title":"Alkene oxidation in water using hydrophobic silica particles derivatized with polyoxometalates as catalysts","authors":"R. Neumann, H. Miller","doi":"10.1039/C39950002277","DOIUrl":null,"url":null,"abstract":"An insoluble catalytic assembly consisting of a silicate xerogel covalently modified with phenyl groups and quaternary ammonium–polyoxometalate ion pairs was used to catalyse the oxidation of alkenes with 30% aqueous hydrogen peroxide in the absence of an organic solvent.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"5 1","pages":"2277-2278"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"44","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950002277","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 44
Abstract
An insoluble catalytic assembly consisting of a silicate xerogel covalently modified with phenyl groups and quaternary ammonium–polyoxometalate ion pairs was used to catalyse the oxidation of alkenes with 30% aqueous hydrogen peroxide in the absence of an organic solvent.