{"title":"Reactions of uranium pentafluoride — The preparation of the first chloridefluorides of uranium (V)","authors":"John A. Berry , John H. Holloway, David Brown","doi":"10.1016/0020-1650(81)80045-1","DOIUrl":null,"url":null,"abstract":"<div><p>The reactions between UF5 and either Me<sub>3</sub>SiCl or UCl<sub>5</sub> in anhydrous acetonitrile yield soluble uranium (V) chloridefluorides. The crystalline complexes UF<sub>5</sub>·2tppo and UCl<sub>2</sub>F<sub>3</sub>·2tppo are obtained in the presence of an excess of triphenylphosphine oxide (tppo).</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80045-1","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800451","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
The reactions between UF5 and either Me3SiCl or UCl5 in anhydrous acetonitrile yield soluble uranium (V) chloridefluorides. The crystalline complexes UF5·2tppo and UCl2F3·2tppo are obtained in the presence of an excess of triphenylphosphine oxide (tppo).
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