Paramagnetic properties of Cuban red mud at low temperatures

IF 0.4 Q4 ENVIRONMENTAL SCIENCES Geology, Geophysics and Environment Pub Date : 2018-12-06 DOI:10.7494/GEOL.2018.44.4.373
V. Shvets
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Abstract

The electron spin resonance (ESR) spectra of Cuban red mud have been measured at three different temperatures: 295 K, 150 K and 77 K. The broad absorption line with resonance fields ∼(1.7–1.8) kOe was observed at all temperatures with values of g-factor from 3.602 to 4.020. The temperature decrease resulted in an absorption line appearance with resonance fields of 3.252 kOe (g = 2.067) at 150 K and 3.339 kOe (g = 2.086) at 77 K. The ESR-signal amplitude with resonance fields ∼(1.7–1.8) kOe decreases and the ESR-signal amplitude in the field ∼3.3 kОе increases with reduction in temperature.
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古巴赤泥在低温下的顺磁性
测定了古巴赤泥在295 K、150 K和77 K三种不同温度下的电子自旋共振(ESR)谱。在所有温度下均观察到共振场为~ (1.7 ~ 1.8)kOe的宽吸收谱线,g因子值为3.602 ~ 4.020。温度降低后的吸收谱线在150 K和77 K的共振场分别为3.252 kOe (g = 2.067)和3.339 kOe (g = 2.086)。随着温度的降低,共振场为~ (1.7 ~ 1.8)kOe的esr信号幅度减小,场为~ 3.3 kОе的esr信号幅度增大。
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