{"title":"X-Ray determination of molecular structures of molybdenum(IV) oxo-complexes. The possibility of a new type of isomerism","authors":"J. Chatt, L. Manojlović-Muir, K. Muir","doi":"10.1039/C29710000655","DOIUrl":null,"url":null,"abstract":"Notable differences between corresponding bond lengths and interbond angles in the complexes blue cis-mer-[MoOCl2(PMe2(Ph)3] and green cis-mer-[MoOCl2(PEt2Ph)3] are caused by ligand repulsions; an explanation of the isomerism of mer-[MoOCl2(PMe2Ph)3] is suggested in terms of the structures of the above complexes.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"77 1","pages":"655-656"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"32","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710000655","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 32
Abstract
Notable differences between corresponding bond lengths and interbond angles in the complexes blue cis-mer-[MoOCl2(PMe2(Ph)3] and green cis-mer-[MoOCl2(PEt2Ph)3] are caused by ligand repulsions; an explanation of the isomerism of mer-[MoOCl2(PMe2Ph)3] is suggested in terms of the structures of the above complexes.
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