A. Bhatt, I. May, V. Volkovich, Melissa E. Hetherington, B. Lewin, R. Thied, N. Ertok
{"title":"Group 15 quaternary alkyl bistriflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes","authors":"A. Bhatt, I. May, V. Volkovich, Melissa E. Hetherington, B. Lewin, R. Thied, N. Ertok","doi":"10.1039/B208968H","DOIUrl":null,"url":null,"abstract":"We report the electrochemical properties of Group 15 quaternary alkyl bistriflimide salts, which have very wide electrochemical windows (between +2.6 and −3.4 V vs. Fc+/Fc for [(Me)4As][N(SO2CF3)2]) when used as supporting electrolytes in MeCN and which can be used for the electrodeposition of very electropositive metals, including Eu, in the molten state.","PeriodicalId":17317,"journal":{"name":"Journal of The Chemical Society-dalton Transactions","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"81","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society-dalton Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/B208968H","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 81
Abstract
We report the electrochemical properties of Group 15 quaternary alkyl bistriflimide salts, which have very wide electrochemical windows (between +2.6 and −3.4 V vs. Fc+/Fc for [(Me)4As][N(SO2CF3)2]) when used as supporting electrolytes in MeCN and which can be used for the electrodeposition of very electropositive metals, including Eu, in the molten state.