Group 15 quaternary alkyl bistriflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes

A. Bhatt, I. May, V. Volkovich, Melissa E. Hetherington, B. Lewin, R. Thied, N. Ertok
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引用次数: 81

Abstract

We report the electrochemical properties of Group 15 quaternary alkyl bistriflimide salts, which have very wide electrochemical windows (between +2.6 and −3.4 V vs. Fc+/Fc for [(Me)4As][N(SO2CF3)2]) when used as supporting electrolytes in MeCN and which can be used for the electrodeposition of very electropositive metals, including Eu, in the molten state.
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15族季烷基双striflimides:离子液体,在电正性金属沉积和作为支撑电解质方面有潜在的应用
我们报道了15族季烷基双striflimide盐的电化学性能,当用作MeCN中的支撑电解质时,它具有非常宽的电化学窗口(在+2.6和−3.4 V之间,[(Me)4As][N(SO2CF3)2]),并且可以用于在熔融状态下电沉积非常正电性的金属,包括Eu。
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