{"title":"Free-radical reactions of halogenated bridged polycyclic compounds. Part XIII. The addition of hydrogen bromide to hexachloromethylenenorbornene","authors":"R. Alexander, D. I. Davies","doi":"10.1039/J39710000896","DOIUrl":null,"url":null,"abstract":"The free-radical addition of hydrogen bromide to hexachloromethylenenorbornene affords a 60 : 40 mixture of 1-bromomethyl-2,3,4,5,5,6-endo-hexachloronorborn-2-ene and 5-endo-bromomethyl-1,2,3,4,7,7-hexachloronorborn-2-ene. The aluminium bromide-catalysed ionic addition gives a 68 : 32 mixture of 5-exo-bromo-1,2,3,4,7,7-hexachloro-5-endo-methylnorborn-2-ene and its 5-endo-bromo-epimer.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"4 1","pages":"896-898"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710000896","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
The free-radical addition of hydrogen bromide to hexachloromethylenenorbornene affords a 60 : 40 mixture of 1-bromomethyl-2,3,4,5,5,6-endo-hexachloronorborn-2-ene and 5-endo-bromomethyl-1,2,3,4,7,7-hexachloronorborn-2-ene. The aluminium bromide-catalysed ionic addition gives a 68 : 32 mixture of 5-exo-bromo-1,2,3,4,7,7-hexachloro-5-endo-methylnorborn-2-ene and its 5-endo-bromo-epimer.
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