Structural and ImpedanceStudies of Nanocrystalline LiCoO2 Particle

K. H. Prasad, Venkat Reddy Julakanti, Gorantla Rangaraju, M. Sumithra, N. Sundaraganesan
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引用次数: 2

Abstract

The most promising power sources for many portable electrical gadgets such as laptop computers, iPod, etc. have been Li-ion Rechargeable batteries. LiCoO2 is the most commercialized cathode material, because of its easy preparation, simple structure, high energy density, low cost, etc. Recently nanoparticles show better electrical and electrochemical properties and hence, could develop improved capacity, energy density and better cycle life Li ion batteries. Synthesis processes play an important role in developing various size and shape of the nanoparticles. In the present work, simple and low cost combustion process was employed and synthesized the lithium cobalt oxide nanoparticles. TG / DTA, XRD, FTIR and Impedance spectroscopy respectively examined thermal behavior, crystalline phase, structure formation and electric conductivity of LiCoO2 particles.
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纳米晶LiCoO2颗粒的结构与阻抗研究
许多便携式电子设备,如笔记本电脑、iPod等,最有前途的电源是锂离子充电电池。LiCoO2具有制备容易、结构简单、能量密度高、成本低等优点,是目前商业化程度最高的正极材料。近年来,纳米颗粒表现出较好的电学和电化学性能,可用于开发容量大、能量密度高、循环寿命长的锂离子电池。合成工艺对纳米颗粒的大小和形状起着重要的作用。本文采用简单、低成本的燃烧工艺合成了钴酸锂纳米颗粒。TG / DTA、XRD、FTIR和阻抗谱分别检测了LiCoO2颗粒的热行为、晶相、结构形成和电导率。
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