{"title":"6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪的合成","authors":"霍欢, 王伯周, 廉鹏, 来蔚鹏, 李辉, 葛忠学","doi":"10.3969/j.issn.1006-9941.2014.02.031","DOIUrl":null,"url":null,"abstract":"以FOX-7和乙二醛为原料,经过两步缩合环化反应和硝化反应,首次设计并合成出了一种新型的呋咱稠环硝胺化合物6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪（PNEIFP）。采用Gaussian 09程序和VLW方程计算PNEIFP的密度、生成焓和爆速分别为2.02 g·cm^-3、724.1 kJ·mol^-1和9681.0 m·s^-1。利用TLC跟踪实验的方法,确定PNEIFP室温下易分解。","PeriodicalId":9983,"journal":{"name":"","volume":"1 1","pages":"274-275"},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"","FirstCategoryId":"1087","ListUrlMain":"https://doi.org/10.3969/j.issn.1006-9941.2014.02.031","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪的合成
以FOX-7和乙二醛为原料,经过两步缩合环化反应和硝化反应,首次设计并合成出了一种新型的呋咱稠环硝胺化合物6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪（PNEIFP）。采用Gaussian 09程序和VLW方程计算PNEIFP的密度、生成焓和爆速分别为2.02 g·cm^-3、724.1 kJ·mol^-1和9681.0 m·s^-1。利用TLC跟踪实验的方法,确定PNEIFP室温下易分解。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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