{"title":"Polyamides incorporating furan moieties. 1. Interfacial polycondensation of 2,2′-bis(5-chloroformyl-2-furyl)propane with 1,6-diaminohexane","authors":"S. Gharbi, A. Gandini","doi":"10.1002/(SICI)1521-4044(19990801)50:8<293::AID-APOL293>3.0.CO;2-I","DOIUrl":null,"url":null,"abstract":"<p>A systematic study, devoted to analyzing the effect of various parameters in the synthesis of furanic aliphatic polyamide by interfacial polycondensation of 2,2′-bis(5-chloroformyl 2-furyl)propane with hexamethylene diamine, is described. The effects of the organic solvent, temperature and phase transfer catalyst type, as well as monomer and sodium hydroxyde concentrations are discussed. The inherent viscosity of the polyamide obtained is higher than those reported in the literature for furanic aliphatic polyamides synthesized from furan-2,5-dicarboxylic acid.</p>","PeriodicalId":7162,"journal":{"name":"Acta Polymerica","volume":"50 8","pages":"293-297"},"PeriodicalIF":0.0000,"publicationDate":"1999-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"23","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Polymerica","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291521-4044%2819990801%2950%3A8%3C293%3A%3AAID-APOL293%3E3.0.CO%3B2-I","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 23
Abstract
A systematic study, devoted to analyzing the effect of various parameters in the synthesis of furanic aliphatic polyamide by interfacial polycondensation of 2,2′-bis(5-chloroformyl 2-furyl)propane with hexamethylene diamine, is described. The effects of the organic solvent, temperature and phase transfer catalyst type, as well as monomer and sodium hydroxyde concentrations are discussed. The inherent viscosity of the polyamide obtained is higher than those reported in the literature for furanic aliphatic polyamides synthesized from furan-2,5-dicarboxylic acid.
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