Preparation and Characterization of Ti-12Mo/X Al2O3 Nano-Composites for Aerospace Applications

A. El-tantawy, H. M. Yehia, Omayma A. Elkady, I. Ghayad
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Abstract

Titanium powder is reinforced with 12 wt. % molybdenum powder, and then the mixed Ti-12%Mo matrix composite powder is reinforced with 5, 10, and 15 wt. % nano Al2O3 by the mechanical milling for 24 hr. The mixed nano-composite powders were cold compacted under 600MPa, then sintered at 1450°C for 90 min. The microstructure and chemical composition of the Ti-12Mo/Al2O3 powders, as well as the fabricated composites, were investigated by both SEM and X-ray diffraction. It has been observed form the SEM studies of the sintered samples that the Al2O3 and Mo particles were homogeneously distributed all over the Ti matrix. All the composites were evaluated by measuring their density, hardness, and wear resistance. The results revealed that the addition of 12 wt. % Mo to pure titanium improves its density due to its high density over than that of the Ti and the good adhesion between them, while the addition of Al2O3 decreases the density of the Ti-12Mo nano-composite. Not only the density of the Ti was improved by the addition of Mo, but also the hardness and wear resistance were also increased. Regardless of the decreasing in the density of Ti-12Mo nano-composite by increasing the Al2O3 wt. %, the hardness and wear resistance were improved up to 5 wt. % Al2O3.
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Ti-12Mo/X - Al2O3纳米复合材料的制备与表征
用12 wt. %的钼粉对钛粉进行增强,然后用5、10、15 wt. %的纳米Al2O3对混合Ti-12%Mo基复合粉末进行机械铣削24小时增强。将Ti-12Mo/Al2O3混合纳米复合粉体在600MPa下进行冷压,在1450℃下烧结90 min。利用扫描电镜和x射线衍射研究了Ti-12Mo/Al2O3混合粉体及其复合材料的微观结构和化学成分。通过对烧结试样的SEM研究发现,Al2O3和Mo颗粒均匀分布在Ti基体上。通过测量复合材料的密度、硬度和耐磨性对其进行了评价。结果表明:在纯钛中添加12 wt. %的Mo,由于其比Ti密度高,且两者之间具有良好的附着力,从而提高了其密度;而Al2O3的添加则降低了Ti- 12mo纳米复合材料的密度。Mo的加入不仅改善了Ti的密度,而且提高了其硬度和耐磨性。随着Al2O3质量分数的增加,Ti-12Mo纳米复合材料的密度降低,但硬度和耐磨性提高到5 wt. %。
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