Electrospun Nanofibers prepared with CdTe QDs, CdTeSe QDs and CdTe/CdS Core-shell QDs

C. Baslak, Ozcan Koysuren, M. Kuş
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Abstract

In this study, a novel method is used to prepare water-soluble CdTe, CdTeSe quantum dots (QDS) and CdTe/CdS core-shell QDs by using Te, Se, NaBH 4 , and CdCl 2 as precursors. Electrospinning method is used to obtain polyvinyl alcohol (PVA)/QDs composite nanofibers. A series of PVA/QDs nanofiber mats with three different QDs content are prepared. Transmission electron microscopy (TEM) and X-ray powder diffraction (XRD) have been used to characterize QD nanoparticles. In addition, for characterization of the composite nanofibers, scanning electron microscopy (SEM) and atomic force microscopy (AFM) have been used. QDs have a good dispersed crystalline structure with an average crystalline size between 2-4 nm. Morphology analyses reveal that the composite nanofibers with an average diameter ranging from 50 to 250 nm are prepared using the electrospinning technique.
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CdTe量子点、CdTeSe量子点和CdTe/CdS核壳量子点制备的电纺丝纳米纤维
本研究以Te、Se、NaBH 4和CdCl 2为前驱体,制备了水溶性CdTe、CdTeSe量子点(QDS)和CdTe/CdS核壳量子点。采用静电纺丝法制备了聚乙烯醇(PVA)/量子点复合纳米纤维。制备了具有三种不同量子点含量的PVA/QDs纳米纤维垫。利用透射电子显微镜(TEM)和x射线粉末衍射仪(XRD)对QD纳米颗粒进行了表征。此外,利用扫描电子显微镜(SEM)和原子力显微镜(AFM)对复合纳米纤维进行了表征。量子点具有良好的分散晶体结构,平均晶粒尺寸在2 ~ 4 nm之间。形貌分析表明,采用静电纺丝技术制备的复合纳米纤维的平均直径在50 ~ 250 nm之间。
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