The viscosity reducers exhibit dispersing ability for resin in heavy oil

IF 1.1 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Canadian Journal of Chemistry Pub Date : 2023-04-06 DOI:10.1139/cjc-2022-0165
Langman Xing, H. Quan, Jinyang Zhao, Xiaomei Huang
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引用次数: 1

Abstract

The viscosity of the heavy oil was closely correlated with its own resin content by comparing of three types of crude oil. In this paper, two novel viscosity reducers with characteristic groups in molecular structures were synthesized for Xinjiang heavy oil, namely viscosity reducer 1 (VR-1) and viscosity reducer 2(VR-2), both of them showed the better viscosity reduction effect on Xinjiang heavy oil and the VR-2 was better than VR-1. The measurement results of UV-visible spectrophotometer and scanning electron microscope (SEM) showed that the VR-2 had the better separation effect for resin than the VR-1. By analyzing the infrared spectrum results of resin molecule, it could be seen that the resin molecule contained more heteroatoms, which could more easily form the stronger hydrogen bonding with VR-2 with more polar groups to result the better resin dispersion effect. Hence, the phenomenon that the VR-1 was not as good as VR-2 in improving fluidity of Xinjiang heavy oil was explained.
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降粘剂在稠油中表现出对树脂的分散能力
通过对三种原油的比较,发现稠油粘度与其自身树脂含量密切相关。本文为新疆稠油合成了两种具有分子结构特征基团的新型降粘剂,即降粘剂1 (VR-1)和降粘剂2(VR-2),两者对新疆稠油的降粘效果均较好,且VR-2优于VR-1。紫外可见分光光度计和扫描电镜(SEM)测试结果表明,VR-2对树脂的分离效果优于VR-1。通过对树脂分子红外光谱结果的分析可知,树脂分子中杂原子较多,更容易与极性基团较多的VR-2形成较强的氢键,从而获得较好的树脂分散效果。从而解释了VR-1在改善新疆稠油流动性方面不如VR-2的现象。
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来源期刊
Canadian Journal of Chemistry
Canadian Journal of Chemistry 化学-化学综合
CiteScore
1.90
自引率
9.10%
发文量
99
审稿时长
1 months
期刊介绍: Published since 1929, the Canadian Journal of Chemistry reports current research findings in all branches of chemistry. It includes the traditional areas of analytical, inorganic, organic, and physical-theoretical chemistry and newer interdisciplinary areas such as materials science, spectroscopy, chemical physics, and biological, medicinal and environmental chemistry. Articles describing original research are welcomed.
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