Structural and Optical Properties of ZnO Nanorods Thin Films Prepared Using Hydrothermal Technique and Effect of growth time

Ahmed Ahmed S. Abed, Sattar J. Qasim, A. F. Abbas
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Abstract

This paper describes, Synthesis of zinc oxide nanorods (ZnO NRs) using hydrothermal technique at different growth time. The structural and morphological properties were characterized by X-ray diffraction (XRD), Energy Dispersive X-Ray (EDX) and Field Emission Scanning Electron Microscope (FE-SEM). The ZnO NRs were obvious hexangular wurtzite structure and preferentially oriented along the c-axis (002) and growth vertically to the substrates. The optical properties were studied. From UV-Visible spectrophotometer and Photoluminescence (PL), the optical band gap energy of all ZnO NRs samples (S1, S2 and S3) were calculated to be (3.425 eV, 3.4 eV, 3.425 eV) respectively. Also, the effect of growth time on ZnO nanorods was studied.
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水热法制备ZnO纳米棒薄膜的结构、光学性质及生长时间的影响
采用水热法在不同生长时间下合成氧化锌纳米棒。采用x射线衍射(XRD)、能量色散x射线(EDX)和场发射扫描电镜(FE-SEM)对其结构和形态进行了表征。ZnO NRs具有明显的六角形纤锌矿结构,优先沿c轴(002)取向,垂直于衬底生长。对其光学性质进行了研究。通过紫外可见分光光度计和光致发光(PL),计算出所有ZnO NRs样品(S1, S2和S3)的光学带隙能分别为(3.425 eV, 3.4 eV, 3.425 eV)。同时,研究了生长时间对ZnO纳米棒的影响。
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