{"title":"The synthesis and single-crystal X-ray structure of the first example of a tridentate, di-orthometallated triphenyl phosphite complex","authors":"R. Bedford, P. A. Chaloner, P. Hitchcock","doi":"10.1039/C39950002049","DOIUrl":null,"url":null,"abstract":"Reaction of [Ir(cod)(py)2][PF6] with triphenyl phosphite leads to the previously reported complex [Ir(cod){P(OC6H4)(OPh)2{P(OPh)3}], but reaction of [Ir(cod){P(OPh)3}Cl] with methyllithium and subsequent treatment with methanol yields the tridentate di-orthometallated complex [IrH(cod){P(OC6H4)2(OPh)}].","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"4 1","pages":"2049-2050"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950002049","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 7
Abstract
Reaction of [Ir(cod)(py)2][PF6] with triphenyl phosphite leads to the previously reported complex [Ir(cod){P(OC6H4)(OPh)2{P(OPh)3}], but reaction of [Ir(cod){P(OPh)3}Cl] with methyllithium and subsequent treatment with methanol yields the tridentate di-orthometallated complex [IrH(cod){P(OC6H4)2(OPh)}].