Studies on fabricating α-Fe2O3 ultrafine particles by LB film technology

Chenglin Liu , Gu Jianhua , Li Yuanguang , Zhong Juhua , Zhang Zhaokui
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引用次数: 2

Abstract

The α-Fe2O3 ultrafine particles were dispersed in the solutions of stearic acid/n-hexane/chloroform by the ultrasonic method, and fabricated by the Langmuir–Blodgett film technology. α-Fe2O3 ultrafine particles/stearic acid composite LB films were characteried by π–A curve, UV-visible absorption spectrum, IR spectrum, small angle X-ray diffraction, TEM and electron diffraction. The results showed the following: the αFe2O3 ultrafine particles were uniformly dispersed in organic solvents; the film-forming characterization of the α-Fe2O3 ultrafine particles/stearic acid monolayer was fine, the α-Fe2O3 ultrafine particles in the composite film had a small orientation; the α-Fe2O3 ultrafine particles/stearic acid composite film had a lamellar structure.

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LB膜技术制备α-Fe2O3超细颗粒的研究
采用超声法将α-Fe2O3超细颗粒分散在硬脂酸/正己烷/氯仿溶液中,并采用Langmuir-Blodgett薄膜技术制备。采用π-A曲线、紫外可见吸收光谱、红外光谱、小角x射线衍射、TEM和电子衍射对α-Fe2O3超细颗粒/硬脂酸复合LB膜进行了表征。结果表明:αFe2O3超细颗粒在有机溶剂中均匀分散;α-Fe2O3超细颗粒/硬脂酸单层成膜表征较细,复合膜中α-Fe2O3超细颗粒取向较小;α-Fe2O3超细颗粒/硬脂酸复合膜呈片层状结构。
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