Insights into the Titania (TiO2) Photocatalysis on the Removal of Phthalic Acid Esters (PAEs) in Water

Norfarahim Mohd Tubillah, S. Chandren
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Abstract

In this era of globalization, plastic is regarded as one of the most versatile innovations, finding its uses ranging from packaging, automotive, agriculture, and construction to the medical and pharmaceutical industries. Unfortunately, the single-use nature of plastics leads to ecological and environmental problems. Among conventional disposal management of plastic waste are landfilling dumping, incineration, and recycling. However, not all plastic waste goes into disposal management and ends up accumulating in lakes, rivers, and seas. In the aquatic environment, the action of photochemical weathering plastics has resulted in the release of chemical additives such as phthalic acid esters (PAEs), an important plasticizer added to plastic products to improve their softness, flexibility, and durability. Nowadays, PAEs have been ubiquitously detected in our environment and numerous organisms are exposed to PAEs to some extent. As PAEs carry endocrine disruptive and carcinogenicity properties, an urgent search for the development of an efficient and effective method to remove PAEs from the environment is needed. As a viable option, titania (TiO2) photocatalysis is a promising tool to combat the PAEs contamination in our environment owing to its high photocatalytic activity, cost-effectiveness, and its ability to totally mineralize PAEs into carbon dioxide and water. Hence, this paper aims to highlight the concerning issue of the contamination of PAEs in our aquatic environments and the summary of the removal of PAEs by TiO2 photocatalysis. This review concerning the significance of knowledge on environmental PAEs would hopefully spark huge interest and future development to tackle this plastic-associated pollutant. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
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二氧化钛(TiO2)光催化去除水中邻苯二甲酸酯(PAEs)的研究进展
在这个全球化的时代,塑料被认为是最通用的创新之一,从包装、汽车、农业、建筑到医疗和制药行业都有它的用途。不幸的是,塑料的一次性使用特性导致了生态和环境问题。传统的塑料垃圾处理管理包括填埋、倾倒、焚烧和回收。然而,并不是所有的塑料垃圾都进入了处理管理,最终积聚在湖泊、河流和海洋中。在水生环境中,光化学风化塑料的作用导致化学添加剂的释放,如邻苯二甲酸酯(PAEs),一种重要的增塑剂添加到塑料制品中,以提高其柔软性,柔韧性和耐久性。如今,PAEs在我们的环境中无处不在,许多生物都在不同程度上暴露于PAEs。由于PAEs具有内分泌干扰和致癌性,迫切需要寻找一种高效、有效的方法从环境中去除PAEs。作为一种可行的选择,二氧化钛(TiO2)光催化由于其高光催化活性、成本效益和将PAEs完全矿化到二氧化碳和水中的能力,是对抗环境中PAEs污染的一种很有前途的工具。因此,本文旨在重点介绍我国水生环境中PAEs污染的相关问题,并对TiO2光催化去除PAEs的研究进展进行综述。这篇关于环境PAEs知识的重要性的综述有望引起人们对这一塑料相关污染物的巨大兴趣和未来的发展。版权所有©2022作者所有,BCREC集团出版。这是一篇基于CC BY-SA许可(https://creativecommons.org/licenses/by-sa/4.0)的开放获取文章。
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