Determination of photo-induced Seebeck coefficient for hot carrier solar cell applications

H. Esmaielpour, D. Suchet, L. Lombez, A. Delamarre, S. Boyer-Richard, A. Beck, A. Le Corre, O. Durand, J. Guillemoles
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引用次数: 1

Abstract

Determination of Seebeck coefficient is a practical technique to investigate the direct conversion of hot carrier energy to electric voltage. However, this study is challenging, especially in nanostructured materials using traditional measurements via heaters and electric contacts. Here, we investigate photo-induced Seebeck effects of InGaAs multi-quantum-well structure via a contact-less measurement (photoluminescence spectroscopy). We have determined thermodynamic properties of hot carriers via fitting the emitted photoluminescence spectra with the generalized Planck's law. We have observed a linear dependence between the gradient of carrier temperature and the quasi-Fermi level splitting of photo-generated hot carriers at various lattice temperatures, which is associated with thermoelectric effects in the system.
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热载流子太阳能电池光致塞贝克系数的测定
塞贝克系数的测定是研究热载子能量直接转化为电压的一种实用技术。然而,这项研究具有挑战性,特别是在纳米结构材料中,使用传统的通过加热器和电接触进行测量。在这里,我们通过无接触测量(光致发光光谱)研究了InGaAs多量子阱结构的光致塞贝克效应。利用广义普朗克定律拟合热载流子的发光光谱,确定了热载流子的热力学性质。我们观察到在不同晶格温度下,载流子温度梯度与光生热载流子的准费米能级分裂之间存在线性关系,这与系统中的热电效应有关。
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