Microstructure formation mechanism of (Al_2O_3+TiB_2+Al_3Ti)/Al composites fabricated by reaction hot pressing

Pub Date : 2004-01-01 DOI:10.4028/0-87849-456-1.1439
Wang Gui-song
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Abstract

Two (Al_2O_3+TiB_2+Al_3Ti)/Al composites were made from Al-B_2O_3-TiO_2 and Al-B-TiO_2 raw powders by hot pressing. The microstructure of the two composites was analyzed by OM, SEM and TEM. The results show that coarse Al_3Ti blocks with size of several tens of micrometers are formed during hot pressing, and the fine equiaxed Al_2O_3 and hexagon TiB_2 particulates are formed simultaneously. On the other hand, there are fine Al_3Ti precipitates in the composite fabricated from Al, B and TiO_2 powders. After extrusion, the coarse Al_3Ti blocks are broken into small pieces. Al_2O_3 particles are formed on the surface of TiO_2 or B_2O_3 powder, TiB_2 particles are formed on B or B_2O_3 powders, and they are fine and dispersively distributed. The formation of coarse Al_3Ti block is resulted from long-distance diffusion of Ti in liquid Al.
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反应热压制备(Al_2O_3+TiB_2+Al_3Ti)/Al复合材料的微观结构形成机理
以Al- b_2o_3 - tio_2和Al- b - tio_2为原料,采用热压法制备了两种(Al_2O_3+TiB_2+Al_3Ti)/Al复合材料。采用OM、SEM和TEM分析了两种复合材料的显微组织。结果表明:在热压过程中,形成了几十微米大小的粗Al_3Ti块,同时形成了细小的等轴Al_2O_3和六边形TiB_2颗粒;另一方面,Al、B和TiO_2粉末制备的复合材料中有细小的Al_3Ti析出。挤压后,粗Al_3Ti块体破碎成小块。Al_2O_3颗粒在TiO_2或B_2O_3粉末表面形成,TiB_2颗粒在B或B_2O_3粉末表面形成,颗粒细小,分布分散。粗Al_3Ti块的形成是由于Ti在液态Al中的远距离扩散所致。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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