Excited state formation in irradiated polyethylene in the presence of aromatic admixtures at low temperature

M. Szadkowska-Nicze, J. Mayer, J. Kroh
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引用次数: 4

Abstract

Radioluminescence from γ and electron pulse-irradiated polyethylene at low temperatures (77–298 K) was investigated. The influence of sample morphology, alkane solvent soaking and aromatic admixtures (naphthalene, pyrene, difenyl etc.) on isothermal and radiothermoluminescence was examined.

The mechanism of charge trapping and radioluminescence generation in irradiated polyethylene is discussed. Fast exciton migration followed by molecular ion rearrangement and recombination seem to be the main processes responsible for excited state formation.

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低温下辐照聚乙烯中芳香族外加剂的激发态形成
研究了低温(77 ~ 298 K)下γ和电子脉冲辐照聚乙烯的辐射发光。考察了样品形貌、烷烃溶剂浸泡和芳香族外加剂(萘、芘、二苯醚等)对等温发光和放热发光的影响。讨论了辐照聚乙烯中电荷捕获和辐射发光的机理。激子的快速迁移和分子离子的重排和重组似乎是激发态形成的主要过程。
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Corrigendum Erratum Announcement Measurement of radiation damage on organic scintillators caused by gamma-rays and its recovery time Radiation effects on crystalline polymers—I. Gamma-radiation-induced crosslinking and structural characterization of polyethylene oxide
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