Geopolymerization Behaviour of Red and White Clays

A. Pathak, Arpana Ranjit, B. Dhakal
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Abstract

Construction is one of the most important activities increasing the demand for Portland cement resulting significant amount of CO2 emission, natural resources degradation, and a high amount of energy consumption. The use of geopolymer has been studied as a potential substitute for Portland cement. Geopolymers are environmentally-friendly binding materials that are produced by the polymerization of alumino-silicates in presence of alkali polysilicates forming Si-O-Al bonds, which are used for several building applications. In this study, red and white clays which contain solid alumino-silicate have shown reactive in presence of an alkaline activator. The addition of lime has shown improvement in the mechanical and physical properties of the geopolymer products. The FTIR analysis and SEM images of the product have shown the formation of aluminosilicate gel in the geopolymeric product. The maximum compressive strength of the geopolymer products RCW and RWL were achieved to be 15.91 and 20.30 MPa, respectively. Such geopolymer products are in good agreement with cementitious products and can be used in building applications.
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红白粘土的地聚合行为
建筑是增加波特兰水泥需求的最重要的活动之一,导致大量的二氧化碳排放,自然资源退化和大量的能源消耗。利用地聚合物作为波特兰水泥的潜在替代品进行了研究。地聚合物是一种环保的结合材料,是由铝硅酸盐在碱聚硅酸盐的存在下聚合而成,形成Si-O-Al键,用于多种建筑应用。在本研究中,含有固体硅酸铝的红色和白色粘土在碱性活化剂的存在下表现出活性。石灰的加入改善了地聚合物产品的机械性能和物理性能。产物的红外光谱分析和扫描电镜图像表明,在地聚合物产物中形成了硅酸铝凝胶。所得地聚合物产品RCW和RWL的最大抗压强度分别为15.91和20.30 MPa。这种地聚合物产品与胶凝产品具有良好的一致性,可用于建筑应用。
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