REMOVAL OF Pb2+ AND Cr3+ USING RICE HUSK AS BIOSORBENT

M. A. Abd El-Aziz, R. A. Al-Masry, H. Hefnawy, A. Khalil
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引用次数: 1

Abstract

: The biosorption process and agricultural waste to treat heavy metals has drawn much attention. This method seems to be a more economical, envchromiummentally friendly, and simple way for removing heavy metals from effluents. The study was conducted to explore the efficiency of the biosorption process utilizing rice husk to remove Pb 2+ and Cr 3+ from synthetic wastewater. Biosorption studies at different operating parameters, such as biosorbent dosage (0.5-5.0 g), pH (pH2– 8), contact time (15-120 minutes), and initial heavy metal concentration (10-100 mg/L), were conducted in batch experiments. The highest performance for Pb 2+ and Cr 3+ biosorption was found at 5.0g biosorbent dosage of spent mushroom compost, unadjusted pH 6, 10 minutes of contact time, and 10 mg/L of initial concentration. The study was well fitted to the Langmuir isotherm model (R 2 > 0.90) for Pb 2+ and Cr 3+ biosorption, which are much greater compared to the Freundlich model. Solvent of 0.1N Sulphuric acid showed higher desorption of Pb 2+ (89%) and Cr 3+ (86%) adsorption-desorption process can be continued till seven cycles efficiently. In conclusion, the rice husk has the potential to be an effective biosorbent for removing Pb 2+ and Cr 3+ from synthetic wastewater.
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稻壳作为生物吸附剂去除Pb2+和Cr3+
生物吸附法和农业废弃物处理重金属的研究备受关注。这种方法似乎是一种更经济、更环保、更简单的去除废水中重金属的方法。研究了稻壳生物吸附工艺对合成废水中pb2 +和cr3 +的去除效果。在不同的操作参数,如生物吸附剂用量(0.5 ~ 5.0 g)、pH (pH2 ~ 8)、接触时间(15 ~ 120分钟)和初始重金属浓度(10 ~ 100 mg/L)下进行了批量实验。废菌堆肥在不调整pH值为6、接触时间为10 min、初始浓度为10 mg/L的条件下,生物吸附剂用量为5.0g,对pb2 +和cr3 +的吸附效果最好。研究结果与Langmuir等温线模型拟合良好(r2 > 0.90), Pb 2+和Cr 3+的生物吸附量远高于Freundlich模型。0.1N硫酸溶液对pb2 +(89%)和cl3 +(86%)有较高的解吸率,吸附-解吸过程可有效持续7个循环。综上所述,稻壳具有作为一种有效的生物吸附剂去除合成废水中的pb2 +和cr3 +的潜力。
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